论文标题：《化工科学与工程前沿》2023年第4期目录

期刊：Frontiers of Chemical Science and Engineering

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Cover illustration

Radioactive iodine exhibits medical values in radiology, but its excessive emissions can cause environmental pollution. Thus, the capture of radioiodine poses significant engineering for the environment and medical radiology. On the cover image, a Th-based MOF (Th-BPYDC) with octahedral structure was synthesized by hydrothermal methods, consisting of 12-linked polyhedral [Th6(μ3-O)₄(μ3-OH)4((H₂O)₆]¹²⁺ clusters, abundant bipyridine units and large cavities allowing diffusion and transport of the guest iodine molecule. Th-BPYDC exhibited an effective uptake capacity for I₂ vapor and dissolved I₂ in cyclohexane, surpassing its corresponding analogue Th−UiO−67. The bipyridine units boosted the adsorption performance, resulting Th-BPYDC with good reusability and high stability. Therefore, the construction of nitrogen-rich bipyridine units on Th-MOF can immensely improve the adsorption capacity for radioiodine, and the feasibility of this strategy provide a new idea for radioiodine capture in spent nuclear fuels treatment. (Xinyi Yang, Xiaolu Liu, Yanfang Liu, Xiao-Feng Wang, Zhongshan Chen, Xiangke Wang, pp. 395-403)

阅读原文请点击“Frontiers of Chemical Science and Engineering Volume 17 Issue 4 ”

Contents

RESEARCH ARTICLE

NiCo₂O₄@quinone-rich N–C core–shell nanowires as composite electrode for electric double layer capacitor

Yanli Fang, Hui Wang, Xuyun Wang, Jianwei Ren, Rongfang Wang

Hierarchical porous carbon derived from one-step self-activation of zinc gluconate for symmetric supercapacitors with high energy density

Junlei Xiao, Hua Zhang, Yifan Wang, Chunmei Zhang, Shuijian He, Shaohua Jiang

Optimizing iodine capture performance by metal–organic framework containing with bipyridine units

Xinyi Yang,Xiaolu Liu,Yanfang Liu,Xiao-Feng Wang,Zhongshan Chen,Xiangke Wang

Zn_xZr/HZSM-5 as efficient catalysts for alkylation of benzene with carbon dioxide

Junjun Cheng, Yitao Zhao, Guohao Xu, Peng Zhang, Xuedong Zhu, Fan Yang

Boehmite-supported CuO as a catalyst for catalytic transfer hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan

Zexing Huang, Zhijuan Zeng, Xiaoting Zhu, Wenguang Zhao, Jing Lei, Qiong Xu, Yongjun Yang, Xianxiang Liu

Efficient acetoin production from pyruvate by engineered Halomonas bluephagenesis whole-cell biocatalysis

Meiyu Zheng, Zhenzhen Cui, Jing Zhang, Jing Fu, Zhiwen Wang, Tao Chen

Oxygen-deficient MoO_x/Ni₃S₂ heterostructure grown on nickel foam as efficient and durable self-supported electrocatalysts for hydrogen evolution reaction

Zihuan Yu, Haiqing Yan, Chaonan Wang, Zheng Wang, Huiqin Yao, Rong Liu, Cheng Li, Shulan Ma

Construction of defect-containing UiO-66/MoSe₂ heterojunctions with superior photocatalytic performance for wastewater treatment and mechanism insight

Xiao Han, Xiaoxuan Wang, Jiafang Wang, Yingjie Xie, Cuiwei Du, Chongfei Yu, Jinglan Feng, Jianhui Sun, Shuying Dong

Removal of nitric oxide from simulated flue gas using aqueous persulfate with activation of ferrous ethylenediaminetetraacetate in the rotating packed bed

Da Guo, Guisheng Qi, Dong Chen, Jiabao Niu, Youzhi Liu, Weizhou Jiao

Simultaneous removal of total oxidizable carbon, phosphate and various metallic ions from H₂O₂ solution with amino-functionalized zirconia as adsorbents

Yitong Wang, Yue Zhang, Li Wang

Bioorthogonal chemistry based on-demand drug delivery system in cancer therapy

Lan Lin, Lai Jiang, En Ren, Gang Liu

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